You can make gtalk chat shortcut on your desktop. It willl initiate a chat with only one click. On click it opens a chat window where you can chat with your friend.
This trick works only in window xp not in window vista.
Here is the method:
1. Right click on Desktop and create a shortcut. ( Right Click - New - Shortcut )
2. Type gtalk:chat?jid= username@ gmail.com in shortcut window.(Username is the username of your friend )
3. Click Ok
.
4. Done.
You can also make shortcut to call your friend for that you have to write gtalk:call?jid= username@ gmail.com.
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